铒玻璃 (Er Yb Glass)

我司的Er,Yb:glass玻璃产品,又称铒玻璃,是一种综合性能良好的激光玻璃。Er3+ , Yb3+共掺杂磷酸盐玻璃(Er, Yb:磷酸盐玻璃)是一种众所周知且常用的活性介质,它发射的激光在1.5 – 1.6微米的“人眼安全”光谱范围内。1540nm激光器正处于人眼安全和光纤通信窗口的位置。这就导致了激光的产生和信号的放大。1540nm激光器已广泛应用于测距仪,雷达,目标识别等领域。磷酸盐玻璃结合了4I13/2Er3+上激光能级 的长寿命(~8 ms)激光能级和与Yb3+共振的低寿命(2-3 ms) 2F5/2激发态。从4I11/2到4I13/2的快速非辐射多声子弛豫由于分别在2F5/2 和4I11/2 能级激发的Yb3+和Er3+离子之间的相互作用,能级大大降低了反向能量转移和上转换损失。Er3+/Yb3+共掺磷酸盐玻璃作为LD泵浦的1540nm人眼安全辐射源,可发射直接用于激光测距仪和电信通信的人眼安全1540nm激光辐射。具有1540nm波长的辐射输出的Er,Ybglass激光器不需要添加额外的组分。Er3+/Yb3+共掺磷酸盐玻璃激光器是一种人眼安全波长激光器。由于其体积小、成本低而备受关注。EAT14:Yb3+,Er3+共掺磷酸盐玻璃,适用于高重复频率(1-6Hz)激光二极管泵浦1535nm激光器。在这种EAT14玻璃中可以实现高Yb3+掺杂。
特点
- 吸收带宽
 - 荧光寿命长
 - 光学质量高
 - 眼睛安全
 - 斜率效率高
 
激光规格
| EAT14 | WM4 | |
| 受激发射的横截面(10-20cm2) | 0.8 | 0.75 | 
| 荧光寿命(毫秒)* | 7.7-8.0 | 7.7-8.2 | 
| 中心激光波长(nm) | 1535 | 1535 | 
光学性质
| EAT14 | WM4 | |
| 折射率(1535nm) | 1.524 | 1.528 | 
| 折射率(d 589.3nm) | 1.532 | 1.536 | 
| 阿贝值 | 66 | 66 | 
| dn / dT(10-6 /℃)(20〜100℃) | -1.72 | -3 | 
热规范
| EAT14 | WM4 | |
| 转变温度 (℃) | 556 | 530 | 
| 软化温度 (℃) | 605 | 573 | 
| 线性热膨胀系数(10 -7/ K)(20〜100℃) | 87 | 82 | 
| 线性热膨胀系数(10-7 / K)(100〜300℃) | 95 | 96 | 
| 光程长度的热系数(10-6/ K)(20〜100℃) | 2.9 | 1.4 | 
| 导热系数(25℃)(W / mK) | 0.7 | 0.7 | 
其他规格
| EAT14 | WM4 | |
| 密度g / cm3 | 3.06 | 2.83 | 
| 化学耐久性(在100℃蒸馏水中的失重率)(μg/ hr.cm2) | 52 | 82 | 
吸收和发射光谱
![]()  | ![]()  | 
| EAT-14发射曲线 | EAT-14吸收曲线 | 
![]()  | ![]()  | 
抛光规格
| 方向公差 | < 0.5° | 
| 厚度/直径公差 | ±0.05 mm | 
| 表面平整度 | <λ/8@632 nm | 
| 波前畸变 | <λ/4@632 nm | 
| 表面质量 | 5-Oct | 
| 平行性 | 10〞 | 
| 垂直性 | 15ˊ | 
| 通光孔径 | >90% | 
| 倒角 | <0.1×45° | 
| 最大尺寸 | dia (3-12.7)×(3-150)mm2 | 
参考文献
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| [2] Langar A , Bouzidi C , Elhouichet H , et al. Er–Yb codoped phosphate glasses with improved gain characteristics for an efficient 1.55μm broadband optical amplifiers[J]. Journal of Luminescence, 2014, 148:249-255. | 
| [3] A C B , A T M , B S R D , et al. Sensitizing effect of Yb 3+ ions on photoluminescence properties of Er 3+ ions in lead phosphate glasses: Optical fiber amplifiers[J]. Optical Materials, 2018, 86:256-269. | 
| [4] Ryabtsev G I , Bezyazychnaya T V , Parastchuk V V , et al. Spectral and temporal properties of diode-pumped Er, Yb: glass laser[J]. Optics Communications, 2005, 252(4-6):301-306. | 
| [5] Francini R , Giovenale F , Grassano U M , et al. Spectroscopy of Er and Er–Yb-doped phosphate glasses[J]. Optical Materials, 2000, 13(4):417-425. | 
| [6] Sendova M , JA Jiménez, Honaman C . Rare earth-dependent trend of the glass transition activation energy of doped phosphate glasses: Calorimetric analysis[J]. Journal of Non-Crystalline Solids, 2016, 450:18-22. | 
| [7] Chen C , He R , Tan Y , et al. Optical ridge waveguides in Er3+/Yb3+ co-doped phosphate glass produced by ion irradiation combined with femtosecond laser ablation for guided-wave green and red upconversion emissions[J]. Optical Materials, 2016. | 
| [8] Balaji S , D Ghosh, Biswas K , et al. Insights into Er 3+ Yb 3+ energy transfer dynamics upon infrared ~1550nm excitation in a low phonon fluoro-tellurite glass system[J]. Journal of Luminescence, 2017, 187:441-448. | 
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| [12] Danger T , Huber G , DeNker B I , et al. Diode-pumped cw laser around 1.54 m using Yb, Er-doped silico-boro-phosphate glass[C]// Conference on Lasers & Electro-optics. IEEE, 1998. | 
| [13] S Jiang, SJ Hamlin, JD Myers,等. High-average-power 1.54-μm Er3+:Yb3+-doped phosphate glass laser. 1996. | 
| [14] Osellame R , Valle G D , Chiodo N , et al. Mode-locked and single-longitudinal-mode waveguide lasers fabricated by femtosecond laser pulses in Er:Yb-doped phosphate glass. IEEE, 2007. | 
| [15] Valles J A , Rebolledo M A , J Cortés. Full characterization of packaged Er-Yb-codoped phosphate glass waveguides[J]. IEEE Journal of Quantum Electronics, 2006, 42(2):152-159. | 
| [16] Aseev V A , Ulyashenko A M , Nikonorov N V , et al. Comparison of highly doped Ytterbium-erbium phosphate and silicate glasses for microchip lasers[C]// International Conference on Advanced Optoelectronics & Lasers. IEEE, 2005. | 
| [17] Qiu T , Li L , Temyanko V , et al. Generation of high power 1535nm light from a short cavity cladding pumped Er:Yb phosphate fiber laser[M]. 2004. | 
| [18] Buchenkov V A , Krylov A A , Mak A A . 12 mJ 10 Hz Diode Pumped A/O Q-switched Yb:Er:Glass Laser[C]// 2018:48-48. | 
| [19] Kalashnikov V L , Shcherbitsky V G , Kuleshov N V , et al. Optimization of passively Q-switched Er:glass laser[C]// Lasers and Electro-Optics, 2002. CLEO ’02. Technical Digest. Summaries of Papers Presented at the. IEEE, 2002. | 
| [20] Simondi-Teisseire B , Viana B , Lejus A M , et al. Room-temperature CW laser operation at ~1.55 μm (eye-safe range) of Yb:Er and Yb:Er:Ce:Ca2Al2SiO7 crystals[J]. IEEE Journal of Quantum Electronics, 1996, 32(11):2004-2009. | 
| [21] Wu R , Hamlin S J , Myers J D , et al. Infrared image studies of diode-pumped Yb3+, Er3+:glass[C]// Conference on Lasers and Electro-Optics. 1996. | 
| [22] Tan F , Yu F , Wang L , et al. Enhancement in Laser Performance of Er3+/Yb3+ Co-doped Phosphate Glass Materials[J]. Journal of Wuhan University of Technology-Mater. Sci. Ed. 2015, 30(3):442-446. | 
| [23] Sattar A , Azzouz I M , Shafik M S , et al. Effect of sensitizers on the optical properties of Er3+ions in erbium glass lasers[C]// Workshop on Photonics & Its Application at Egyptian Engineering Faculties & Institutes. IEEE, 2002. | 
| [24] Kervevan L , Gilles H , Girard S , et al. Self-mixing laser Doppler velocimetry with a dual-polarization Yb:Er glass laser[J]. Applied Physics B, 2007, 86(1):169-176. | 
| [25] Karlsson G , Laurell F , Tellefsen J , et al. Development and characterization of Yb-Er laser glass for high average power laser diode pumping[J]. Applied Physics B, 2002, 75(1):41-46. | 
| [26] Vitkin V , Krylov A , Polishchuk A , et al. 40 Hz 1.3 mJ Q-switched Yb:Er:glass Laser[C]// 2018:50-50. | 
| [27] Bhardwaj A , Agrawal L , Pal S , et al. Optimization of passively Q -switched Er:Yb:Cr:phosphate glass laser: theoretical analysis and experimental results[J]. Applied Physics B, 2007, 86(2):293-301. | 
| [28] Kalashnikov V L , Shcherbitsky V G , Kuleshov N V , et al. Pulse energy optimization of passively Q-switched flash-lamp pumped Er:glass laser[J]. Applied Physics B, 2002, 75(1):35-39. | 
| [29] Summaries of papers presented at the Conference on Lasers and Electro-optics. 1999. | 
| [30] Third Workshop on Photonics and its Application at Egyptian Engineering Faculties and Institutes (Cat. No.02EX509)[C]// Workshop on Photonics & Its Application at Egyptian Engineering Faculties & Institutes. IEEE, 2002. | 
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